[Pd2(dba)3] x dba

Tris(dibenzylideneacetone)dipalladium(0)

[Pd2(dba)3] x dba

Chemical properties

Chemical formula

C51H42O3Pd2

Empirical formula

[Pd2(dba)3] x dba

Molecular weight [g/mol]

915.73

Metal

Pd

Theoretical metal content [%]

16

Physical state

crystalline

Color

dark purple

Metal purity [%]

99.95

Safety Information

H317, H411

Handling & storage information

Handling information

Avoid formation of respirable particles. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.


Storage information

Do not store above 25°C (77°F). Store in a tightly closed original container, protected from direct sunlight in a dry, cool and well-ventilated area.

Applications & References

Palladium catalyzed conversion of aryl chlorides and triflates to nitroaromatics.

 

Reference: J. Am. Chem. Soc. 2009, 131, 12898 (DOI: 10.1021/ja905768k)

Site selective sp³ palladium catalyzed direct arylation for a rapid derivatization of heterocyclic compounds.

 

Reference: J. Am. Chem. Soc. 2008, 130, 3266. (DOI: 10.1021/ja710451s)

One-pot ketoindoline synthesis by Palladium catalyzed g-arylation of b,g-unsaturated ketones.

 

Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529)

Asymmetric synthesis of indolines by Palladium catalyzed arylation of b,g-unsaturated ketones.

Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529)

Suzuki cross coupling of aryl chorides with arylboronic acids.

Reference: Angew. Chem. Int. Ed. 1998, 37, 3387. (DOI: 10.1002/(SICI)1521-3773(19981231)37:24<3387::AID-ANIE3387>3.0.CO;2-P)

Efficient method for Suzuki-Miyaura reaction of lithium triisopropyl 2-pyridylborates and aryl chlorides.

 

Reference: Angew. Chem. Int. Ed. 2008, 48, 4695. (DOI: 10.1002/anie.200801465)

Palladium catalyzed aminocarbonylation of aryl halides.

 

Reference: J. Am. Chem. Soc. 2013, 135, 16841. (DOI: 10.1021/ja4098093)

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